Photogeneration of Manganese(III) from Luminescent Manganese(II) Complexes with Thiacalixarene Ligands: Synthesis, Structures and Photophysical Properties
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چکیده
منابع مشابه
Discrete polynuclear manganese(ii) complexes with thiacalixarene ligands: synthesis, structures and photophysical properties.
The synthesis, crystal structure and photophysical properties of the new compound [Mn4(ThiaSO2)2F][K(18-crown-6)], ThiaSO2 = p-tert-butylsulphonylcalix[4]arene, are presented and compared to the ones of [Mn4(ThiaSO2)2F]K. The strong orange luminescence is attributed to the Mn(2+) centred (4)T1→(6)A1 transition. Its temperature and pressure dependence and quenching by molecular dioxygen are repo...
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2018
ISSN: 1434-1948
DOI: 10.1002/ejic.201801104